Dipolar molecules inside C70: an electric field-driven room-temperature single-molecule switch.
نویسندگان
چکیده
We propose a two-state electric field-driven room-temperature single-molecule switch based on a dipolar molecule enclosed inside ellipsoidal fullerene C70. We show that the two low-energy minima of the molecular dipole inside the C70 cage provide distinguishable molecular states of the system that can be switched by application of an external electric field.
منابع مشابه
Dipolar and nonpolar altitudinal molecular rotors mounted on an Au(111) surface.
We describe the preparation of a compound whose molecules consist of two metal sandwich stands carrying tentacles with affinity to metal surfaces and holding an axle that carries a dipolar or a nonpolar rotator. The dipolar rotor exists as three pairs of enantiomers, rapidly interconverting at room temperature. When mounted on a gold surface, each molecule represents a chiral altitudinal rotor,...
متن کاملGround-State Depletion Microscopy: Detection Sensitivity of Single-Molecule Optical Absorption at Room Temperature
Optical studies of single molecules in ambient environments, which have led to broad applications, are primarily based on fluorescence detection. Direct detection of optical absorption with single-molecule sensitivity at room temperature is difficult because absorption is not a background-freemeasurement and is often complicated by sample scattering. Here we report ground-state depletionmicrosc...
متن کاملMagnetoelectrostatic trapping of ground state OH molecules.
We report magnetic confinement of neutral, ground state OH at a density of approximately 3 x 10(3) cm(-3) and temperature of approximately 30 mK. An adjustable electric field sufficiently large to polarize the OH is superimposed on the trap in various geometries, making an overall potential arising from both Zeeman and Stark effects. An effective molecular Hamiltonian is constructed, with Monte...
متن کاملORGANIC PHOTOCONDUCTOR TTF-TCNQ (TETRATHIAFULVALENETETRACYANOQUINODIMETHANE): A POTENTIAL ROOM TEMPERATURE INFRARED DETECTOR AT 10 ?m H. R. Mohajeri Moghaddam* and N. Peyghambarian
The absorption properties of charge transfer organic semiconductor TTF-TCNQ (tetrathiafulvalene-tetracyanoquhodimete ) filmsdeposited on KBr singlecrystal, quartz and glass substrates in far infrared have been investigated. An absorption edge at ?10 ??m was observed. Photoconductivity, photoconduction efficiency and gain and photocarrier's lifetime have been measured. The results show an el...
متن کاملTwo-dimensional trapping of dipolar molecules in time-varying electric fields.
Simultaneous two-dimensional trapping of neutral dipolar molecules in low- and high-field seeking states is analyzed. A trapping potential of the order of 20 mK can be produced for molecules such as ND3 with time-dependent electric fields. The analysis is in agreement with an experiment where slow molecules with longitudinal velocities of the order of 20 m/s are guided between four 50 cm long r...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Physical chemistry chemical physics : PCCP
دوره 18 48 شماره
صفحات -
تاریخ انتشار 2016